The equations are listed in the technical note:
http://www.digitalglobe.c...chnote_raduse_v1.pdf
You can use ENVI's Quickbird radiance tool to get to radiance and then the 'Conversion to Top-of-the-Atmosphere reflectance' equation. Use the 'general equation' that ignores atmospheric effects.
Or you can perform atmospheric correction with a tool like FLAASH which returns atmospherically corrected reflectance.