EO-1 ALI is a supported format in ENVI 5.3:
http://www.harrisgeospatial.com/docs/...
You can use the Radiometric Calibration tool to convert the data to TOA radiance or reflectance:
http://www.harrisgeospatial.com/docs/...
If you have a license for the Atmospheric correction module, which includes FLAASH and Quac, you can then calibrate to surface reflectance, or one of the built-in tools to convert to relative reflectance:
http://www.harrisgeospatial.com/docs/...