If your output is a 3 band RGB TIFF, then it will be difficult to convert the TIFF to a single band classification. Do you have access to IDL? You might have a look at this tech tip:
http://www.ittvis.com/ser...echtip.asp?ttid=4377
If your file is a single band TIFF, you might be able to convert it to classification by going to Edit ENVI Header and changing the file type to 'ENVI Classification' in the header. This will prompt you to enter the number of classes in the file (+ unclassified) and you can assign colors in this dialog.