sorry, in my last message I was wrong. For the Maximum Likelihood Classification, ENVI calculates the discriminant functions for each pixel gi(x). The probability is gi(x)/(sum over i of all gi(x)). So it seems that using tools as "math band" it is possible to calculate the probabilities (or exporting to some other package such as grid in arc/info to carry the computing of the probabilities.
There is more detauils in
http://www.rsinc.com/serv...asp?ttid=1793&pv=yes