Perhaps this HA could help:
http://www.exelisvis.com/Support/Help...
Especially the last part:
Calculating fractional reflectance from FLAASH scaled reflectance:
Using Band Math (under Basic Tools in the main ENVI menu), type the expression:
float(b1)/10,000
where 10,000 is the specified output scale factor found in the FLAASH dialog under Advanced Settings -> Output Scale Factor. The above expression should yield reflectance values of 0-1.0.