Here is what I have garnered from various sites and sources and based upon what I have found in the DIMAP file:
Zenith angle = 180 - VIEWING_ANGLE (see ENVI help file)
It appears that the azimuth angle is calculated from the SCENE_ORIENTATION value, i.e. (https://www.doria.fi/bitstream/handle/10024/62221/enhanced.pdf?sequence=1):
For left looking acquisitions: Azimuth angle = 270+SCENE_ORIENTATION
For right looking acquisions: Azimuth angle = 90 + SCENE_ORIENTATION
For additional information, please see the DIMAP dictionary (
http://www.spotimage.fr/d...ry/pdf/SPOTView.pdf)