ENVI doesn't have a specific calibration tool for RapidEye but calibrations are fairly easy to do by hand if you know the equations to use. First, you will need to apply a scale factor (using Band Math) to convert the DNs to radiance as described in the RapidEye documentation:
http://www.rapideye.de/up...age_Products_FAQ.pdf
The document also describes how to calculate TOA reflectance. If you want to perform atmospheric correction to get reflectance, you can then use something like FLAASH, Quac, or one of the generic tools in ENVI under Calibration utilities such as empirical line (requires field collected data), dark subtraction, log residuals or IARR, or flat field to get relative reflectance.