You refer to the 'toolbox' so I assume you are using ENVI 5 vs. Classic. Since you don't have a ground-truth image my first inclination would be to do an estimated accuracy assessment using ground-truth ROIs based on visual identification of sites instead, but a previous post (
http://www.exelisvis.com/Support/Foru...) seemed to indicate that tool was not available in ENVI 5. So I'll have to think on that a bit more.
Regarding why you cannot find the 'Confusion Matrix Using Ground Truth Image" tool, I am not aware of any special licenses/extensions needed to access that tool so if it is not showing in the toolbox under the Classification -> Post Classification folder I would recommend you contact tech support.