1. If the images are an ENVI format edit the header file (using a text editor) to include wavelengths info. Or edit the header file using ENVI, which would be an easier method.
http://www.exelisvis.com/...ENVIHeaderFiles.html
http://www.exelisvis.com/...formation.html#Edit2
2. The simplest method would be to take the difference between the two images. But that will rely upon having the exact same image dimensions, and it would only make sense to do so if the pixels are geo-referenced exactly. ENVI's layer stacking method might get you there. It will determine the overlap, and re-sample as necessary. Essentially this is just a change detection workflow, which ENVI have a built-in tool for that.
http://www.exelisvis.com/...ChangeDetection.html
Hope that helps
Cheers
Josh