The BIN size cannot currently be controlled in ENVI. We already reported such request to the development so it would be perhaps available in a future version of the product.
However it is possible (if you have an ENVI+IDL license) to control this value using the following IDL routine: HISTROGRAM. I added a link to the IDL documentation for this routine
http://www.exelisvis.com/docs/HISTOGR...