What's probably happening here is that your material spectra from the hourglass workflow and the library spectra are using different units in the x and/or y direction. In this case, the material spectra look so different from all library spectra that it is impossible to find a better or worse match. You can fix this by choosing,in the Spectral Analyst dialog,Options > Edit (x,y) Scale Factors. For example, say your input image has pixel values in units of reflectance between 0 and 10,000 (like lots of images that have been atmospherically corrected in FLAASH will have), with wavelength units in nm. But your spectral library has reflectance values between 0 and 1, and wavelengths in micrometers. You will want to enter an X Data Multiplier (wavelength) of 0.001 to convert from nm to micrometers. You will also want to enter a Y Data Multiplier (reflectance) of 0.0001 to convert from 10,000 to 1. You will want to check my math here.
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