Hi Puneeth,
If you have your ENVI header and you know the pixel Easting, pixel Northing, x-pixel size, and y-pixel size, you can do a quick calculation to find the values at the four corners with the pixel size and number of pixels. Or, you can use the ConvertPixelToMap coordinates to do all of that using ENVI + IDL. Here is a link to the documentation for that task:
http://www.exelisvis.com/docs/ENVICon...